80. Leighton Meester

Leighton Meester moved beyond Gossip Girl this year and made herself a presence on the big screen while breaking out even more on the red carpet with her bold style. She took on Minka Kelly in The Roommate and also sang alongside Gwyneth Paltrow in Country Strong. On the fashion front, Leighton became a spokesperson for Missoni and appeared in a Vera Wang fragrance campaign. The actress maintained her single status for quite a while following her split from Sebastian Stan, as she focuses on her acting and music careers.

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